New structure directing agent in the synthesis of ZSM-5 zeolite

Autores

  • Marcelo Luís Mignoni URI Autor
  • Paloma Reato Autor
  • Kátia Bernardo-Gusmão Autor

Palavras-chave:

Ionic liquid, Structure-directing agents, Zeolites, ZSM-5, Synthesis

Resumo

This work describes the use of a novel structure-directing agent for the preparation of a pure MFI zeolitic material. The ionic liquid 1-(4-phenylbenzyl)-3-methylimidazolium chloride [PhBzMIm.Cl] was used to obtain this zeolitic material. The method described in this study involves the use of SiO2 (silica source), NaOH as a mineralizing agent, Na2Al2O4 as an aluminum source, and H2O as the reaction solvent. The described method is advantageous because it uses a mild temperature (150 °C) and uses a structure-directing agent that is easy to synthesize and is classified within green chemistry. The method aims to obtain zeolitic materials with a Si/Al ratio = 50 and a pure and crystalline MFI topology, which makes this process technically and commercially attractive.

Referências

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[5] Shiyun Sang, Fuxiang Chang, Zhongmin Liu, Changqing He, Yanli He, Lei Xu, Difference of ZSM-5 zeolites synthesized with various templates, Catalysis Today,Volumes 93–95, 2004.

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[7] Sethia, G., Dangi, G. P., Jetwani, A. L., Somani, R. S., Bajaj, H. C., & Jasra, R. V. (2010). Equilibrium and Dynamic Adsorption of Carbon Monoxide and Nitrogen on ZSM-5 with Different SiO2/Al2O3 Ratio. Separation Science and Technology, 45(3), 413–420.

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Publicado

03-11-2025

Edição

Seção

Síntese e caracterização de catalisadores e adsorventes