Characterization of copper-based nanocatalysts supported on metal oxides for the selective hydrogenation of furfural

Autores

  • Bruno Rhian Universidade Federal da Bahia Autor
  • Pedro A. Mâcedo Universidade Federal da Bahia Autor
  • Geciane A. dos Santos Universidade Federal da Bahia Autor
  • Maria L. A. da Silva Universidade Federal da Bahia Autor
  • Caio L. S. Silva Universidade Federal da Bahia Autor

Palavras-chave:

Furfural; Hydrogenation; Cupper; nanocatalysts

Resumo

Furfural is a biomass-derived platform molecule of growing interest for the production of renewable fuels and value-added chemicals, such as furfuryl alcohol (FOL) and 2-methylfuran (2-MF), via catalytic hydrogenation. In this work, copper-based nanocatalysts supported on ZnO, MgO, and Al₂O₃ were synthesized through a co-precipitation method adapted from the literature, aiming to provide an environmentally friendly alternative to the traditional copper chromite catalyst, known for its toxicity. The synthesized materials were characterized by transmission electron microscopy (TEM), nitrogen adsorption-desorption (BET method), and Fourier transform infrared spectroscopy (FTIR). TEM analysis revealed distinct morphologies depending on the support, including nanowire structures and core–shell configurations. The catalysts exhibited relatively low specific surface areas, ranging from 8 to 37 m2/g, consistent with reports for similar metal oxides.

Referências

1. RIBEIRO, Paulo Roberto et al. Furfural-da biomassa ao laboratório de química orgânica. Química Nova, v. 35, p. 1046-1051, 2012.

2. LIU, Jun et al. Multiple Cores‐Shell Structured Cu@ SiO2 Ultrathin Leaf‐Shaped Nanocomposite: Facile Fabrication and Excellent Selective Catalytic Hydrogenation Performance. ChemistrySelect, v. 3, n. 17, p. 4643-4652, 2018.

3. BRADY, Rania et al. UV filters and high refractive index materials based on carboxymethyl cellulose sodium and CuO@ ZnO core/shell nanoparticles. Scientific Reports, v. 13, n. 1, p. 21159, 2023.

4. NAGARAJA, B. M. et al. A highly efficient Cu/MgO catalyst for vapour phase hydrogenation of furfural to furfuryl alcohol. Catalysis communications, v. 4, n. 6, p. 287-293, 2003.

5. YANG, Xiaohai et al. Construction of novel Cu/ZnO-Al2O3 composites for furfural hydrogenation: The role of Al components. Applied Catalysis A: General, v. 561, p. 78-86, 2018.

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Publicado

03-11-2025

Edição

Seção

Síntese e caracterização de catalisadores e adsorventes